Coal analysis can be reported to a range of different "basis" depending on the purpose of the analysis. For example, "as received" or "as sampled" basis is used to understand the concentration of analytes in a coal including all the surface moisture. In contrast, reporting results on a "dry, ash-free" basis can be useful to understanding the rank of the coal, particularly when reviewing Volatile Matter, Hydrogen or Carbon concentrations. There may also be commercial reasons why a particular moisture basis is required, notably when a coal contract is written to a specified moisture basis, for example "2.5% moisture" basis
When the basis changes the associated analytical results will also change. Consequently, when comparing results it is important to compare them on the same basis.
There are a range of commonly used coal bases, each of which has a prescribed abbreviation. Bases include:
The relationship between the various bases is provided in the figure below.
The general equation for conversion from one moisture basis to another moisture basis is as follows:
General Equation:
100 – moisture basis required . analyte result as analyzed = analyte at required moisture basis
100 – moisture basis as analyzed
Example 1: You have a set of air-dried results where the as-analyzed Moisture is 2.0% (ad) and Ash is 12.0% (ad). For a contract you are required to report the Ash to a Moisture basis of 3.0% basis.
100 – Moisture (required basis) . Ash result (ad) = Ash result (at required basis)
100 – Moisture (ad)
(100 – 3.0) . 12.0 = 11.9% (ad)
(100 – 2.0)
Example 2: You are required to report an Ash value to Total Moisture (ar) basis where the air dried Moisture is 2.0% (ad), the air dried Ash is 12.0% (ad) and the Total Moisture is 10% (ar).
100 – Moisture (ar) . Ash result (ad) = Ash (ar)
100 – Moisture (ad)
(100 – 10.0) . 12.0 = 11.0% (ar)
(100 – 2.0)
Example 3: You analyzed a sample which has the following characteristics: Moisture 2.0% (ad), Ash 12.0% (ad) and Volatile Matter 29.5% (ad). You are required to calculate the Volatile Matter to a dry, ash free (daf) basis.
100 – Moisture (daf) + Ash (daf) . Volatile Matter (ad) = Volatile Matter (daf)
100 – Moisture (ad) + Ash (ad)
(100 – (0 + 0)) . 29.5 = 34.3 (daf)
(100 – (2.0 + 12.0))
The numerators and denominators used to convert a result from one basis to another basis are provided in the table below. These are multiplied by the existing analyte result to produce the analyte result at the required basis.
Existing basis | Desired basis | |||
---|---|---|---|---|
As received | Air Dried | Dry | Dry Ash Free | |
As received | 100 – M(ad) 100 – M(ar) |
100 100 – M(ar) |
100 100–(M(ar)+A(ar)) |
|
Air Dried | 100 – M(ar) 100 – M(ad) |
100 100 – M(ad) |
100 100–(M(ad)+A(ad)) |
|
Dry | 100 –M(ar) 100 |
100 – M(ad) 100 |
100 100–A(d) |
|
Dry Ash Free | 100-(M(ar)+A(ar)) 100 |
100-(M(ad)+A(ad)) 100 |
100 – A(d) 100 |
For information on how to determine in-situ moisture, refer to Moisture in Coal.
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